First thing we request:

Go into Stardock Central, go into Free Stuff and download and run SmartException.

If the game crashes, it'll create a .CRA file in a ZIP file (SE isn't the friendliest tool out there but it's inside the ZIP it creates).  If you can post the contents of the .CRA file, we'll know what line of code it crashed on.

Also, please post the beginning page of your debug.err and then the last several lines of the debug.err.